4.7 Article

Striped Poly(diacetylene) Monolayers Control Adsorption of Polyelectrolytes and Proteins on 2D Materials and Elastomers

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Summary: The study demonstrates the transfer of self-assembled and photopolymerized striped monolayers of diacetylene amphiphiles from graphite to polydimethylsiloxane (PDMS), allowing precise control over the surface chemistry of elastomers used in various applications. This process creates sub-nm thick precision polymer films with functional patterns, which influence interfacial wetting, reactivity, and template adsorption of ultranarrow gold nanowires. The polarized fluorescence emission of polydiacetylenes reveals polymer location, orientation, and environment, while also preventing engulfment, a common issue in PDMS functionalization.

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