Journal
GREEN CHEMISTRY
Volume 18, Issue 18, Pages 4974-4981Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc00859c
Keywords
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Funding
- China Scholarship Fund
- National Natural Science Fund of China [31200448]
- U.S. National Science Foundation [DMR-1252611]
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Grafting from RAFT polymerization was carried out on lignin using three soybean oil-derived methacrylate monomers toward sustainable biocomposites. These grafted biocomposites showed structure-dependent thermal and mechanical properties. The presence of hydrogen bonding between secondary amides resulted in grafted copolymers with much higher glass transition temperature and different tensile behaviors. Epoxy resins prepared from epoxide-containing grafted polymers exhibited much tougher mechanical properties compared with uncured biocomposites.
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