Journal
GREEN CHEMISTRY
Volume 18, Issue 8, Pages 2416-2423Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc02893k
Keywords
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Funding
- Strategic Environmental Research and Development Program [SERDP WP-2214]
- Air Force Office of Scientific Research
- Office of Naval Research
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Carvacrol is a renewable phenol that can be derived from abundant components of pine resin. To demonstrate the utility of carvacrol for polymer applications, a bisphenol was synthesized from carvacrol and converted to both a cyanate ester resin (CarvCy) and polycarbonate. A cured resin disk prepared from CarvCy exhibited a T-g of 224 degrees C and a water uptake of only 0.7% after being immersed in 85 degrees C water for four days. The wet T-g of the material was only 3 degrees C lower than the dry T-g showing that the cured resin was virtually unaffected by exposure to hot water. Despite the presence of aliphatic groups on the aromatic rings, the cured resin exhibited good thermal stability with only 5% weight loss at 390 degrees C. The polycarbonate prepared from carvacrol had M-n = 10 200, M-w/M-n = 1.60, T-g = 119 degrees C, and even better thermal stability than the cyanate ester with 5% weight loss observed at 421 degrees C. The results provide compelling evidence that the sustainable phenol carvacrol can be used as a platform molecule for the generation of high performance polymers with exceptional properties.
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