Journal
GREEN CHEMISTRY
Volume 18, Issue 22, Pages 5999-6003Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc02285e
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Funding
- State Key Program of the National Natural Science Foundation of China [21436007]
- Key Basic Research Projects of Science and Technology Commission of Shanghai [14JC1403100]
- Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning [ZXDF160002]
- Central Laboratory of SESE in SJTU
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A non-noble ternary skeletal CuAlZn catalyst was designed for direct hydrogenation of ethyl levulinate (EL) to 1,4-pentanediol (1,4-PDO). 98% yield of 1,4-PDO, which is the highest yield achieved by heterogeneous catalysts so far, was obtained over CuAlZn-3.5 h. Zn in the skeletal alloy was found as a vital promoter for adjusting the selectivity of 1,4-PDO production.
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