Journal
GREEN CHEMISTRY
Volume 18, Issue 7, Pages 1965-1975Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc01976a
Keywords
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Funding
- DTU
- Biomass for the 21st Century (B21st) - Danish National Advanced Technology Foundation
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Lignin has been pyrolyzed in a continuous fast pyrolysis reactor and the vapor was subsequently upgraded in situ over a downstream, close coupled HZSM-5 catalyst in a fixed bed reactor. The effect of the catalyst temperature on the HZSM-5 upgrading of lignin derived pyrolysis vapor was investigated. The results show that a high catalyst temperature (600 degrees C) is required in order to produce oxygen free aromatics. At a catalyst temperature of 600 degrees C, an organic liquid product, which contains 70 wt% oxygen free aromatics (mainly benzene and toluene), is obtained. However, the yield of the organic liquid is reduced from 27.6 wt%(daf) without a catalyst to 5.7 wt%(daf) (600 degrees C catalyst temperature). The energy recovery in the liquid organics is 8.7% (600 degrees C catalyst temperature), compared to the 33.0% energy recovery in the organic liquid from the non-catalytic run. Oxygen is removed from the pyrolysis vapor mainly in the form of H2O and CO when using the HZSM-5 zeolite, which is less optimal compared to if CO2 was the product. The organic liquid fraction, obtained from the 600 degrees C catalyst temperature experiment, has a low oxygen content of 4.0 wt%, compared to the 23.4 wt% oxygen content in the untreated organic liquid.
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