4.7 Article

Progress and challenges pertaining to the earthly-abundant electrocatalytic materials for oxygen evolution reaction

Journal

SUSTAINABLE MATERIALS AND TECHNOLOGIES
Volume 28, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.susmat.2021.e00252

Keywords

Tafel plot; overpotential; electrocatalyst; stability; oxygen evolution reaction; theoretical modeling

Funding

  1. The World Academy of Sciences (TWAS)
  2. South Africa's National Research Foundation (NRF)
  3. Department of Science and Technology (DST) [105453, SFH160618172220]
  4. NRF: S&FExtended Support for Scholarships and Fellowships [MND190603441389, 121108]

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This article discusses the conceptual study of oxygen evolution reaction and electrocatalytic kinetics, as well as providing an overview of synthesizing catalysts for the reaction. Emphasis is placed on describing different families of compounds used for synthesizing high-performance catalysts, with a discussion on important future perspectives for advancement in the field.
The scarcity and high cost of commercial noblemetal-based materials necessitate the need for synthesizing alternative electrocatalysts for oxygen evolution reaction (OER). Many efforts put in place in addressing this problem have resulted in huge successes by employing different routes for synthesizing electrocatalysts, using different families of atoms and compounds. In this regard, this review describes the conceptual study of OER and an overview of electrocatalytic kinetics and theoretical modeling for oxygen evolution reaction. For in-depth understanding, a comprehensive and general overview of the recent developments in the OER electrocatalysts and efficient methods of testing the stabilities of catalysts to obtain reliable results are given. The study also includes some tutorial manuals for describing various parameters needed in electrochemical OER processes. We do hope they will be the useful guiding principles for the newcomers in this field. Interestingly, the emphasis is focused on describing different families of compounds used to synthesize high-performance OER electrocatalysts: which include transition metal compounds, polyoxometalates, carbon nanotubes, single atoms, layered double hydroxide, and non-metal compounds. Conclusively, important future perspectives to foster the advancement of this field are discussed. (C) 2021 Elsevier B.V. All rights reserved.

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