Self-Standing, Robust Membranes Made of Cellulose Nanocrystals (CNCs) and a Protic Ionic Liquid: Toward Sustainable Electrolytes for Fuel Cells

Energy-conversion devices based on the phenomenon of proton conduction, for example, polymer electrolyte membrane fuel cells (PEMFCs), require low cost and sustainable electrolytes with high ionic conductivity and good mechanical properties under anhydrous conditions and at temperatures up to 150 degrees C. Biopolymers possess an intrinsic thermomechanical stability but an insufficient proton conductivity in the dry state, which however may be imparted by a protic ionic liquid (PIL). This work presents the preparation and properties of composite membranes made of cellulose nanocrystals (CNCs) and a PIL. The membranes are thermally stable and display an ionic conductivity within the range 10(-4)-10(-3) S/cm for temperatures between 120 and 160 degrees C. Moreover, the analysis of the biopolymer's apparent dimensions at nanoscale reveals a dependence of the CNCs' defects, twisting, and aggregation in the presence of the PIL. Preliminary tests using a simple fuel cell setup demonstrate a response of the membranes to the inlet of H-2 gas, with a generation of electrical current. These findings provide a solid groundwork for further development and future studies of biopolymer/PIL electrolytes for energy applications.

Automated summary

This study presents composite membranes made of cellulose nanocrystals and a protic ionic liquid, which exhibit improved proton conductivity of biopolymers under high temperature and anhydrous conditions. The membranes display good thermal stability and ionic conductivity, with analysis showing that the properties are influenced by defects, twisting, and aggregation of nanocrystals at the nanoscale. Preliminary fuel cell tests demonstrate that the membranes respond to H-2 gas and generate electrical current, laying a solid groundwork for further development of biopolymer/protic ionic liquid electrolytes for energy applications.