Journal
MATERIALS TODAY ENERGY
Volume 21, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.mtener.2021.100721
Keywords
Fe-N-C; Active sites; Oxygen reduction reaction; Zinc-air batteries
Funding
- National Natural Science Founda-tion of China [51974114, 51672075, 21908049, 51804116]
- Hunan Provincial Natural Science Foundation of China [2020JJ4175]
- China Postdoctoral Science Foundation [2020M682560]
- Science and technology innovation program of Hunan province [2020RC2024]
- Fundamental Research Funds for the Central Universities
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In this study, a cooperative protection strategy was proposed to fabricate Fe-N-x/Fe3C@NC with abundant Fe-N-x moieties and highly dispersed Fe3C nanodots, displaying high activity and robust durability towards oxygen reduction reaction. This strategy offers guidance for the preparation of high-performance transition metal-N-C-based catalysts for energy storage and conversion systems.
As promising alternatives to noble metal catalysts such as platinum-based electrocatalysts, Fe/N co-doped carbon (Fe-N-C) materials attract extensive attention because of their high activity and good durability. It is acknowledged that non-crystalline Fe-N-x moieties and crystalline iron-based nano-particles as important active sites, largely determine the catalytic performance of Fe-N-C catalysts. However, the design and preparation of Fe-N-C catalyst still suffer from insufficient effective active sites because of the inevitable agglomeration phenomenon. In our work, from the perspective of minimizing catalyst size and prohibiting catalyst agglomeration, we put forward a co-operative protection strategy and successfully fabricate abundant Fe-N-x moieties and highly dispersed hyperfine Fe3C nanodots jointly decorated N-doped carbon framework (Fe-N-x/Fe3C@NC). By systematic characterization and analysis, we find the formation of these abundant active sites (Fe-N-x moieties and Fe3C nanodots) originates from the co-operative protection of different components in original precursors. As a result, the obtained product, Fe3C/Fe-N-x@NC hybrid displays high activity and robust durability towards oxygen reduction reaction (ORR) in both alkaline and acid medium. When employed as the cathode catalyst for Zn-air batteries, Fe3C/Fe-N-x@NC also exhibits comparable performance to that of commercial Pt/C catalyst. Clearly, our adopted strategy provides a good guidance on the preparation of high-performance transition metal-N-C-based catalysts for energy storage and conversion systems. (C) 2021 Elsevier Ltd. All rights reserved.
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