Journal
ENERGY STORAGE MATERIALS
Volume 39, Issue -, Pages 347-353Publisher
ELSEVIER
DOI: 10.1016/j.ensm.2021.04.037
Keywords
MXene; 3D Bode analysis; high rate; impedance; pseudocapacitance
Funding
- Fluid Interface Reactions, Structures and Transport (FIRST) Center, an Energy Frontier Research Center (EFRC) - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences
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In this study, three-dimensional Bode analysis was used to investigate the charge storage dynamics of Ti3C2Tx and Ti2CTx MXenes, revealing pseudocapacitive behavior of Ti3C2Tx in acidic electrolyte and a double-layer charge storage mechanism in neutral electrolyte. The results obtained from 3D Bode analysis were in good agreement with kinetic analyses using voltammetry methods.
Pseudocapacitive materials offer high charge storage capacities at high rates with charging time scales of tens of seconds to a few minutes. Voltammetry methods are extensively employed in understanding complex charge storage processes in pseudocapacitive materials. In this study, three-dimensional (3D) Bode analysis is employed in investigating charge storage dynamics of two-dimensional (2D) titanium carbides, Ti3C2Tx and Ti2CTx MXenes. Ti(3)C(2)Tx is used as a model system due to its high metallic conductivity and electrolyte-dependent capacitive/redox charge storage properties to better understand the charge storage dynamics in acidic and neutral electrolytes. In electrochemical impedance measurements, Ti3C2Tx /acidic electrolyte interface shows a high real capacitance accompanied by a low phase angle at specific potentials in the capacitive domain of frequencies (10 mHz to 1 Hz), demonstrating pseudocapacitive behavior. On the other hand, Ti3C2Tx/neutral electrolyte interface exhibits invariant low real capacitance with high phase angle values in the low frequency regime, indicating a double-layer charge storage mechanism. The charge storage dynamics of MXene electrodes determined using 3D Bode analysis corroborates well with the kinetic analyses using voltammetry methods.
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