4.8 Article

Photopatternable hydroxide ion electrolyte for solid-state micro-supercapacitors

Journal

JOULE
Volume 5, Issue 9, Pages 2466-2478

Publisher

CELL PRESS
DOI: 10.1016/j.joule.2021.07.003

Keywords

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Funding

  1. Office of Naval Research [N00014-19-1-2113]
  2. CNRS through the MITI interdisciplinary programs
  3. ANR STORE-EX
  4. French network on electrochemical energy storage (RS2E)

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This research presents a solid electrolyte that can be patterned using standard lithography, providing a stable and high-conductivity option for energy storage in microelectronics. By utilizing a combination of materials, high-resolution, solid-state VN micro-super-capacitors can be fabricated on a scalable basis for single or multiple devices.
Electrochemical energy storage (EES) devices that provide high power and energy for micropower systems are considered to be essential for developing micro/nano electronics such as nanorobotics, environmental sensors, and connected smart electronics. One promising research direction in this field has been to develop on-chip EES devices whose length scales integrate with those of miniaturized electronic devices. In the work described here, we provide the first report of a hydroxide-ion-conducting solid electrolyte that can be patterned using standard lithography. By combining a negative photoresist with a polymerizable ionic liquid, weobtain a thermally and dimensionally stable, hydroxide-ion-conducting solid electrolyte with a conductivity of 10 mS cm(-1). Patterning the solid electrolyte directly on interdigitated vanadium nitride (VN) electrodes enables a scalable fabrication approach for producing high-resolution, solid-state VN micro-super-capacitors (MSC) in both single and multiple devices.

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