4.7 Article

Preparation and oil absorption performance of polyacrylonitrile / reduced graphene oxide composite porous material

Journal

JOURNAL OF WATER PROCESS ENGINEERING
Volume 41, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jwpe.2021.102092

Keywords

Polyacrylonitrile fiber; Graphene oxide; Porous material; Oil-water separation; Recycling

Funding

  1. Scientific Research Fund of Taiyuan University of Technology [20504020203]
  2. Shanxi Provincial Foundation for Returned Scholars, China [2017048]

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The PAN/RGO composite porous material prepared in this study showed excellent adsorption capacity towards oil and organic solvents, as well as resistance to chemical corrosion. It is a cost-effective, efficient, and environmentally friendly material for oil-water separation and waste oil recycling.
In this study, the PAN/RGO composite porous material was prepared through a combination of hydrothermal reaction and freeze-drying used waste polyacrylonitrile fiber (PAN) as the raw material and reduced graphene oxide (RGO) as the reinforcing phase. The resulting PAN/RGO composite porous material has obvious 3D porous structure that made up of the PAN fibers as three-dimensional skeleton and RGO served as the reinforcing and bonding material between the fibers. The PAN/RGO displayed excellent adsorption capacity towards oil or organic solvent and resistance to chemical corrosion such as acid and salt. The maximum adsorption amount of oil was up to 42.8-177.2 times its own weight and the oil retention rate was reach 96.8 %. Meanwhile, the PAN/ RGO exhibited good reusability and the adsorption efficiency still maintained at about 90 % after nine recycling tests. This research provides an economical, effective and environmentally friendly material for oil-water separation and recycling of waste oil.

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