Journal
APPLIED MATERIALS TODAY
Volume 23, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apmt.2021.101056
Keywords
Shape memory photopolymer; recovery stress; Thermal stability; Flame retardancy; Ultrahigh < em > T < sub > g <; sub ><; em >
Categories
Funding
- US National Science Foundation [OIA-1946231]
- Louisiana Board of Regents for the Louisiana Materials Design Alliance (LAMDA), National Science Foundation [1736136]
- NASA [NNX16AQ93A, NASA/LEQSF(2016-19)-Phase3-10]
- Division Of Human Resource Development
- Direct For Education and Human Resources [1736136] Funding Source: National Science Foundation
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This study introduces an intrinsically flame-retardant high-temperature shape memory photopolymer with ultrahigh glass transition temperature and record-breaking recovery stress, addressing the need for photopolymers with high Tg, flame-retardancy, and high recovery stress in various industries. The novel HTSMP demonstrates excellent thermal stability, intrinsic flame retardancy, and 3D printability, making it promising for applications in deployable structures, damage self-healing, actuators, proppants, 4D printing, and robotics.
Here we report an intrinsically flame-retardant high-temperature shape memory photopolymer (HTSMP) with ultrahigh glass transition temperature (Tg) of 280(circle)C and record-breaking recovery stress of 35.3 MPa. Photopolymers have been widely used in 3D printing structures with high resolution by technologies such as digital light processing (DLP). However, a bottleneck persists in the lack of photopolymer inks integrated with high Tg, flame-retardancy, and high recovery stress, which are highly desired in several sectors such as in aerospace, automotive, construction, oil&gas, and electronic industries. In addition, photopolymers usually have low mechanical strength and toughness, limiting their use in critical load bearing structures. In this study, a photopolymerizable isocyanurate triacrylate and a phosphine oxide photo-initiator were firstly formulated to prepare HTSMP through a facile two-step ultraviolet (UV) curing and thermal curing process. The UV curing makes the HTSMP 3D printable. After the unusual high temperature (280 C-circle for 3 h) post-curing, the HTSMP network was highly crosslinked and uniform, which enhanced the strength and toughness. Additionally, the synergy between isocyanurate and phosphine oxide contributed excellent thermal stability and high flame-retardancy to the HTSPM, which cannot be ignited upon ten-second ignition for two times. A condensed-phase mechanism for flame-retardancy was also identified. With the ultrahigh Tg, record-high recovery stress and energy output, excellent thermal stability, intrinsic flame retardancy, and 3D printability, this new multifunctional HTSMP has a great potential in various applications, such as in deployable structures, damage self-healing, actuators, proppants, 4D printing, and robotics. (c) 2021 Elsevier Ltd. All rights reserved.
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