Journal
NATURE REVIEWS CHEMISTRY
Volume 5, Issue 6, Pages 422-439Publisher
NATURE PORTFOLIO
DOI: 10.1038/s41570-021-00276-3
Keywords
-
Categories
Funding
- Friedrich-Alexander-Universitat Erlangen-Nurnberg (FAU)
- Fonds der Chemischen Industrie im Verband der Chemischen Industrie e.V. (Liebig Fellowship)
- Research Corporation for Science Advancement (RCSA)
- Fulbright Germany
Ask authors/readers for more resources
This review discusses the importance of molecules with different resonance structures in various applications of chemistry, as well as the role of ambidentate/ambiphilic or cooperative ligands in coordination chemistry. By analyzing the historical development of organic zwitterions and various ligands and their metal complexes, new principles for ligand design are proposed, with potential future research directions highlighted.
Molecules with different resonance structures of similar importance, such as heterocumulenes and mesoionics, are prominent in many applications of chemistry, including `click chemistry', photochemistry, switching and sensing. In coordination chemistry, similar chameleonic/schizophrenic entities are referred to as ambidentate/ambiphilic or cooperative ligands. Examples of these had remained, for a long time, limited to a handful of archetypal compounds that were mere curiosities. In this Review, we describe annbiphilicity- or, rather, 'charge frustration' - as a general guiding principle for ligand design and functional group transfer. We first give a historical account of organic zwitterions and discuss their electronic structures and applications. Our discussion then focuses on zwitterionic ligands and their metal complexes, such as those of ylidic and redox-active ligands. Finally, we present new approaches to single-atom transfer using cumulated small molecules and outline emerging areas, such as bond activation and stable donor-acceptor ligand systems for reversible 1e(-) chemistry or switching.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available