Journal
MOLECULAR CATALYSIS
Volume 514, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.mcat.2021.111837
Keywords
Ferrrocene; Urea; Hematite; Magnetite; ORR
Categories
Ask authors/readers for more resources
The in situ synthesis of PFUA was reported by reacting specific compounds, which were then pyrolyzed to obtain magnetically materials with different properties. Among them, PFUA pyrolyzed at 800 degrees C showed the best electrocatalytic activity towards ORR.
Herein, we report the in situ synthesis of poly (ferrocene-urea) (PFUA) by reacting ferrocene diacylazide and tris (4-aminophenyl) amine. The formation of urea linkages between the precursors was confirmed by Fourier transform Infrared (FTIR) spectroscopy. The synthesized PFUA was pyrolyzed at different temperatures under Argon atmosphere to obtain hematite at 600 degrees C and magnetite embedded N-doped carbons at 800 and 1000 degrees C. Both hematite and magnetite was found to have particulate morphology embedded on porous N-doped carbon. The N-doping into the carbon matrix was confirmed by X-ray photoelectron spectroscopy (XPS). Further, their electrocatalytic activity towards oxygen reduction reaction (ORR) was carried out under standard conditions. PFUA pyrolyzed at 800 degrees C was found to exhibit better ORR activity than the other samples. The improved electrocatalytic activity toward ORR can be ascribed to the reductive environment generated during the thermal treatment of the urea linkages (formed between FDA and TAPA) which controls the structural transformation of the hematite phase to magnetite phase of iron oxide with creation of oxygen vacancies with improved Fe2+ to Fe3+ ratio.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available