Journal
MOLECULAR CATALYSIS
Volume 514, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.mcat.2021.111664
Keywords
Ultrasound assisted synthesis; Hydrogen generation; Biomass photocatalytic valorization; Nano-engineered titanium dioxide; Benzyl alcohol; HMF selective photo-oxidation
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The study utilized an ultrasound-assisted ultra-wet impregnation synthetic approach to successfully decorate the surface of TiO2 nanoparticles with nanometric clusters of mixed cupric and cuprous oxides, creating TiO2-CuOx nanocomposite. This nanocomposite demonstrated enhanced hydrogen generation capability and high efficiency in the selective partial oxidation of biomass-derived chemicals, outperforming the benchmark commercial TiO2 P25.
The herein presented ultrasound-assisted ultra-wet (US-UWet) impregnation synthetic approach was followed in order to avoid the drawbacks of the conventional wet impregnation synthesis. The goal was to homogeneously decorate the surface of the TiO2 nanoparticles with nanometric sized (< 4 nm) clusters of mixed cupric and cuprous oxides. The physicochemical features of the nanocomposite (TiO2-CuOx) were determined by highangle annular dark-field scanning transmission electron microscope (HAADF-STEM), high-resolution transmission electron microscopy (HR-TEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (XRD), and Diffuse reflectance (DR) spectroscopy. TiO2-CuOx showed an enhanced and continuous capability to generate molecular hydrogen upon low power ultraviolet irradiation. The benchmark commercial TiO2 P25 did not reveal any H2 formation under these conditions. TiO2-CuOx presented also a high efficiency for the additives-free selective partial oxidation of two well established biomass derived model platform chemicals/building blocks, 5-hydroxymethylfurfural (HMF) and benzyl alcohol (BnOH) to the value-added chemicals 2,5-diformylfuran (DFF) and benzyl aldehyde (PhCHO), respectively. The nanocomposite showed higher DFF and PhCHO yield compared to P25.
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