RSM-Based Preparation and Photoelectrocatalytic Performance Study of RGO/TiO2 NTs Photoelectrode

In this paper, reduced graphene oxide (RGO) was prepared by a modified Hummers method and chemical reduction method, and an RGO/TiO2 NTs (RGO/TiO2 nanotubes) photoelectrode was prepared by the electrochemical deposition method. The as-prepared RGO/TiO2 NTs were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD), and their photocatalytic activities were investigated by measuring the degradation of methylene blue (MB) under simulated solar light irradiation. The SEM and XRD results indicated that the original tubular structure of TiO2-NTs was not changed after RGO modification. The surface of the TiO2 NTs photoelectrode was covered with a non-uniform, flake-shaped reduced graphene oxide film. The thickness of the RGO/TiO2 NTs was increased to about 22.60 nm. The impedance of the RGO/TiO2 NTs was smaller than that of the TiO2 NT photoelectrode. The optimal preparation conditions of RGO/TiO2 NT photoelectrodes were investigated by using a single factor method and response surface method. The best preparation conditions were as follows: deposition potential at 1.19 V, deposition time of 10.27 min, and deposition temperature at 24.94 degrees C.

Automated summary

In this study, reduced graphene oxide (RGO) was prepared using a modified method, and an RGO/TiO2 nanotubes photoelectrode was developed. The photocatalytic activities of the RGO/TiO2 NTs were examined, showing that the structure of TiO2-NTs remained unchanged after RGO modification, with an increased thickness of the RGO/TiO2 NTs and lower impedance compared to TiO2 NT photoelectrode. Optimal preparation conditions for RGO/TiO2 NT photoelectrodes were determined through single factor and response surface methods.