4.6 Article

Flexible Textile Direct-Current Generator Based on the Tribovoltaic Effect at Dynamic Metal-Semiconducting Polymer Interfaces

Journal

ACS ENERGY LETTERS
Volume 6, Issue 7, Pages 2442-2450

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.1c00288

Keywords

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Funding

  1. National Key Research and Development Program of China [2016YFA0202702]
  2. Youth Innovation Promotion Association of CAS

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A flexible textile-based DC generator utilizing the tribovoltaic effect has been developed, which can efficiently harvest mechanical energies to power self-powered wearable electronics. The generator is based on the dynamic Schottky junction between an Al slider and a poly(3,4-ethylenedioxythiophene)-coated textile, providing a voltage output of approximately 0.45-0.70 V. Connecting multiple generators in series can increase the voltage and current output, demonstrating the potential for continuous power supply to electronic devices without the need for conditioning circuits.
Generation of direct current (DC) from mechanical kinetic energies is crucial for realizing self-powered wearable electronics. Here, we report a flexible textile-based DC generator based on the tribovoltaic effect at a dynamic metal-semiconducting polymer interface. The tribovoltaic effect refers to a phenomenon in which an energy quantum is released once an atom-atom bond is formed at the dynamic interface of two contacting materials; such released binding energy excites electron-hole pairs at metal-semiconductor interfaces or semiconductor-semiconductor pn junctions. This textile DC generator, based on the dynamic Schottky junction between an Al slider and a poly(3,4-ethylenedioxythiophene)-coated textile, can output a voltage of approximately 0.45-0.70 V. The voltage and current can be increased by simply connecting multiple generators in series or in parallel. Seven generators in series can power an electronic watch constantly without any conditioning circuit. These findings offer an efficient strategy for harvesting mechanical energies and realizing self-powered electronics.

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