4.7 Article

Microstructural evolution and corrosion behavior of Ti-6Al-4V alloy fabricated by laser metal deposition for dental applications

Journal

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
Volume 14, Issue -, Pages 1459-1472

Publisher

ELSEVIER
DOI: 10.1016/j.jmrt.2021.07.006

Keywords

Laser metal deposition; Ti-6Al-4V; Scanning strategy; Microstructural evolution; Corrosion behavior

Funding

  1. National Natural Science Foundation of China [51871050]
  2. Fundamental Research Funds for the Central Universities [N180203019, N2002019]
  3. Liaoning Revitalization Talents Program [XLYC1907158]
  4. Natural Science Foundation Project of Liaoning Province [2020-MS-150, 2018225059]
  5. Shenyang Science and Technology Funded Project [RC190290]

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The microstructural evolution and corrosion behavior of Ti-6Al-4V alloy fabricated by laser metal deposition (LMD) in simulated saliva were investigated in this study. The results showed that one-way scanning exhibited higher corrosion resistance than cross-scanning, but both were inferior to the wrought samples. Additionally, the higher content of b phase in the LMD-ed parts improved corrosion resistance compared to the conventional wrought counterpart.
In this study, microstructural evolution and corrosion behavior of Ti-6Al-4V (TC4) alloy fabricated by laser metal deposition (LMD) were investigated in simulated saliva at 37 degrees C as a function of scanning strategies. One-way scanning possessed a higher corrosion resistance than cross-scanning, but both of those were inferior to the wrought one. Compared with conventional wrought counterpart, the higher content of b phase improved the corrosion resistance. Results of MotteSchottky and potentiostatic tests indicated that the passive film upon the surfaces of all the samples exhibited an N-type semiconductor structure and instantaneous nucleation. Of these, the LMD-ed parts displayed a lower donor concentration, higher vacancy diffusion coefficient, and thicker passive film than the wrought samples. XPS analysis revealed that the double-layer structure of passive film leads to a dense protective layer on the surface while the oxide contents of the three were different. (C) 2021 The Authors. Published by Elsevier B.V.

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