Permeability Evolution of Fractures in Shale in the Presence of Supercritical CO2

We experimentally examined the impact of supercritical carbon dioxide (scCO(2)) on fracture permeability and fracture surface characteristics in shales of various compositions. We measured permeability and fracture normal displacement at different effective stresses using both argon and scCO(2) as pore fluids. Both natural fractures and saw cuts in intact samples were used in our study. The permeability and fracture normal displacement decrease after multiple loading/unloading cycles, apparently as the result of inelastic compaction. In samples with high carbonate content, we observe an increase in permeability and fracture surface degradation after more than 3.5 days of exposure to scCO(2), apparently due to carbonate dissolution. We demonstrate that the sensitivity of permeability to effective normal stress correlates well with the fracture normal displacement. The dependence of permeability on effective normal stress increases after exposure to scCO(2) as the fracture surface became more compliant.

Automated summary

The experimental study found that supercritical carbon dioxide (scCO(2)) has an impact on fracture permeability and surface characteristics in shales of various compositions, especially in samples with high carbonate content. Permeability may increase and fracture surface may degrade with longer exposure time. The sensitivity of permeability to effective normal stress also increases as the fracture surface becomes more compliant after exposure to scCO(2).