Microstructural design of printed graphite electrodes for lithium-ion batteries

Performance properties of lithium-ion battery electrodes; capacity, rate and lifetime, are determined by the design of the coating composite microstructure. The internal pore structure and electronic networks for high coat weight graphite electrodes are manipulated through changes in the ink rheological properties, and through an syringe dispensing printing process. The rheological properties of a water-based, high viscosity graphite ink were optimised using a secondary solvent for the rheological requirements of a syringe dispensing method. The microstructure of high coat-weight battery electrodes produced from printing and tape cast methods were compared and the electrochemical performance evaluated. Cross sectional analysis of the slurry cast coatings showed improved component homogeneity, lower graphite alignment with 0.1% to 10% weight increase of the secondary solvent, with a corresponding change in tortuosity of the electrodes of 5.3-2.8. Improved cycle life is observed with a printed electrode containing an embedded electrolyte channel. Performance properties were elucidated through charge discharge, GITT and PEIS measurements. Improved electronic conductivities, exchange currents and diffusion coefficients were observed for the syringe deposited electrode. This digital deposition process for manufacturing electrodes shows promise for further optimisation of electrodes for long-life, high energy density batteries. CO 2021 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http:// creativecommons.org/licenses/by/4.0/).

Automated summary

The performance properties of lithium-ion battery electrodes are determined by the design of the coating composite microstructure. This study optimized the rheological properties of the graphite ink and utilized a specific printing process to manipulate the internal pore structure and electronic networks of high coat weight electrodes, resulting in improved performance and cycle life. Depositing electrodes via syringe showed enhanced electronic conductivities and diffusion coefficients, leading to better cycle life and higher energy density.