Journal
MATERIALS RESEARCH LETTERS
Volume 9, Issue 9, Pages 382-390Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/21663831.2021.1949401
Keywords
Sodium ion battery; phosphide; electrospinning; heterostructure
Categories
Funding
- National Natural Science Foundation of China [U20A20249]
- Science and Technology Program of Guangdong Province of China [2020A050515007]
- Science and Technology Development Fund [0019/2019/AGJ]
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The well-dispersed MoP nanoparticles confined in a carbon nanofiber skeleton with the introduction of titania exhibited superior cycling stability and performance. This design provides a simple and efficient way for the preparation of phosphides.
MoP is a promising anode material choice for alkali ion storage ascribed to its superior electrochemical performance. However, severe volume expansion and poor stability limited its output performance. Here, well-dispersed MoP nanoparticles are confined in carbon nanofiber skeleton by facile electrospinning method, further introduction of titania enhances the interfacial reaction and structure stability. As a result, the carbon nanofiber encapsulated MoP/TiO2 composite exhibited 150 mAh g(-1) at 1 A g(-1) for 4000 cycles, without obvious capacity decay. The homogenous dispersion and heterostructure construction contribute to its superior performance. This design provides a simple way for the phosphide preparation.
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