4.7 Article

Active Sites in a Heterogeneous Organometallic Catalyst for the Polymerization of Ethylene

Related references

Note: Only part of the references are listed.
Article Chemistry, Physical

Methylaluminoxane's Molecular Cousin: A Well-defined and Complete Al-Activator for Molecular Olefin Polymerization Catalysts

Francesco Zaccaria et al.

Summary: A novel Al-H-Al+[B(C6F5)(4)]- molecular cocatalyst with high efficiency in activation and impurity scavenging for molecular olefin polymerization catalysis is reported, offering a promising avenue for further tuning and representing an unprecedented molecular activator in the field.

ACS CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants

Uddhav Kanbur et al.

Summary: This study introduces a new catalytic method that converts polyolefins in discarded plastics into high-value compounds, overcoming the limitations of traditional carbon-carbon bond cleavage methods. Economic analysis shows that this method is cost-effective and has the potential to address the plastic-waste crisis.
Article Chemistry, Physical

Catalyst Deactivation Processes during 1-Hexene Polymerization

Anuj Joshi et al.

ACS CATALYSIS (2020)

Review Chemistry, Multidisciplinary

Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts

Jeremie D. A. Pelletier et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Article Chemistry, Physical

Supported Single-Site Organometallic Catalysts for the Synthesis of High-Performance Polyolefins

Madelyn M. Stalzer et al.

CATALYSIS LETTERS (2015)

Review Chemistry, Multidisciplinary

Design Strategies for the Molecular Level Synthesis of Supported Catalysts

Staci L. Wegener et al.

ACCOUNTS OF CHEMICAL RESEARCH (2012)

Article Chemistry, Multidisciplinary

γ-Alumina: The Essential and Unexpected Role of Water for the Structure, Stability, and Reactivity of Defect Sites

Raphael Wischert et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

Cationic Alkylaluminum-Complexed Zirconocene Hydrides as Participants in Olefin Polymerization Catalysis

Steven M. Baldwin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Chemistry, Multidisciplinary

Stopped-Flow NMR: Determining the Kinetics of [rac-(C2H4(1-indenyl)2)ZrMe][MeB(C6F5)3]-Catalyzed Polymerization of 1-Hexene by Direct Observation

Matthew D. Christianson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Review Chemistry, Inorganic & Nuclear

The Chemistry of Catalyst Activation: The Case of Group 4 Polymerization Catalysts

Manfred Bochmann

ORGANOMETALLICS (2010)

Article Chemistry, Multidisciplinary

Alkylaluminum-Complexed Zirconocene Hydrides: Identification of Hydride-Bridged Species by NMR Spectroscopy

Steven M. Baldwin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

Article Chemistry, Inorganic & Nuclear

Formation and Structures of Hafnocene Complexes in MAO- and AlBu3i/CPh3[B(C6F5)4]-Activated Systems

Konstantin P. Bryliakov et al.

ORGANOMETALLICS (2008)

Article Chemistry, Multidisciplinary

Molecular understanding of alumina supported single-site catalysts by a combination of experiment and theory

Jerome Joubert et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)

Article Multidisciplinary Sciences

Catalytic production of olefin block copolymers via chain shuttling polymerization

DJ Arriola et al.

SCIENCE (2006)

Review Chemistry, Multidisciplinary

Bound but not gagged -: immobilizing single-site α-olefin polymerization catalysts

JR Severn et al.

CHEMICAL REVIEWS (2005)

Article Polymer Science

The discovery of metallocene catalysts and their present state of the art

W Kaminsky

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY (2004)

Review Chemistry, Multidisciplinary

Reaction of vinyl chloride with group 4 metal olefin polymerization catalysts

RA Stockland et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

Article Chemistry, Multidisciplinary

Fifty years of Ziegler catalysts: Consequences and development of an invention

G Wilke

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)

Review Chemistry, Multidisciplinary

Homogeneous and heterogeneous catalysis: Bridging the gap through surface organometallic chemistry

C Coperet et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)

Article Chemistry, Multidisciplinary

A 2H-labeling scheme for active-site counts in metallocene-catalyzed alkene polymerization

ZX Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)

Review Chemistry, Multidisciplinary

Heterogeneous single-site catalysts for olefin polymerization

GG Hlatky

CHEMICAL REVIEWS (2000)