4.6 Article

Sewage Sludge Derived Materials for CO2 Adsorption

Journal

APPLIED SCIENCES-BASEL
Volume 11, Issue 15, Pages -

Publisher

MDPI
DOI: 10.3390/app11157139

Keywords

adsorbents; carbon dioxide; char; pyrolysis; sewage sludge

Funding

  1. Romanian Ministry of Research, Innovation and Digitization, under NUCLEU Program [9N/2019, PN 19 11 03 01]
  2. Romanian Ministry Education and Research, UEFISCDI Authority [PN-III-P1-1.2-PCCDI-2017-0776, 36 PCCDI/15.03.2018]

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The study investigated the use of sewage-sludge-derived materials for CO2 adsorption, with promising results in terms of adsorption capacity. The materials were structurally and texturally characterized, and the efficiency of CO2 adsorption was evaluated using a homemade system coupled with a gas chromatograph. The study concluded that the sewage sludge derived material could be a promising solution for CO2 reduction and waste disposal.
The study tried to contribute to solving two serious environmental issues: CO2 reducing and sewage sludge disposal. Thus, sewage-sludge-derived materials were obtained in order to be evaluated for CO2 adsorption capacity. Therefore, the char resulted after the sewage sludge pyrolysis was subjected to oxidation and chemical activation processes by using different quantities of alkaline hydroxide. One of the obtained materials, activated with a lower quantity of alkaline hydroxide, was also treated with acid chloride. Further, the materials were structural and texturally characterized, and material treated with acid chloride was used for CO2 adsorption tests, due to high surface area and pore volume. The handmade system coupled to a gas chromatograph allowed the adsorption efficiency evaluation using different feed gases (rich and poor in CO2) by completed purge of pipe line and on-line check. Additionally, the adsorption capacity, separation efficiency, and CO2 recovery were calculated. Taking into account the values for adsorption capacity (separation efficiency and CO2 recovery), it can be concluded that the sewage sludge derived material could be a promising solution for CO2 reduction and waste disposal.

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