Mineralogical Prediction on the Flotation Behavior of Copper and Molybdenum Minerals from Blended Cu-Mo Ores in Seawater

The copper ore in Chilean copper porphyry deposits is often associated with molybdenum minerals. This copper-molybdenum (Cu-Mo) sulfide ore is generally mined from various locations in the mining site; thus, the mineral composition, oxidation degree, mineral particle size, and grade vary. Therefore, in the mining operation, it is common to blend the ores mined from various spots and then process them using flotation. In this study, the floatability of five types of Cu-Mo ores and the blending of these ores in seawater was investigated. The oxidation degree of these Cu-Mo ores was evaluated, and the correlation between flotation recovery and oxidation degree is presented. Furthermore, the flotation kinetics of each Cu-Mo ore were calculated based on a mineralogical analysis using mineral liberation analysis (MLA). A mineralogical prediction model was proposed to estimate the flotation behavior of blended Cu-Mo ore as a function of the flotation behavior of each Cu-Mo ore. The flotation results show that the recovery of copper and molybdenum decreased with the increasing copper oxidization degree. In addition, the recovery of blended ore can be predicted via the flotation rate equation, using the maximum recovery (R-max) and flotation rate coefficient (k) determined from the flotation rate analysis of each ore before blending. It was found that R-max and k of the respective minerals slightly decreased with increasing the degree of copper oxidation. Moreover, R-max varied greatly depending on the mineral species. The total copper and molybdenum recovery were strongly affected by the degree of copper oxidation as the mineral fraction in the ore varied greatly depending upon the degree of oxidation.

Automated summary

The study investigates the floatability of copper-molybdenum (Cu-Mo) ores in Chilean copper porphyry deposits and the behavior of blended ores in seawater. It was found that the recovery of copper and molybdenum decreases with the increasing copper oxidation degree, and the recovery of blended ore can be predicted using the flotation rate equation. Additionally, the total copper and molybdenum recovery are strongly affected by the degree of copper oxidation, as the mineral fraction in the ore varies greatly depending on the oxidation degree.