Journal
MINERALS
Volume 11, Issue 6, Pages -Publisher
MDPI
DOI: 10.3390/min11060620
Keywords
Pb solubility; Pb2+ activity; precipitation; ion pairs; thermodynamic models
Funding
- National Institute of Food and Agriculture [NYC-125400]
- Agriculture and Food Research Initiative (AFRI) from the USDA National Institute of Food and Agriculture [2016-67019-25265, 1009565]
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Lead solubility in contaminated soils and water is limited by dissolution-precipitation reactions of secondary mineral phases. The addition of phosphate results in the precipitation of lead phosphate minerals, preventing the formation of lead sulfate and carbonate minerals. Thermodynamic models may underestimate lead solubility and overestimate free lead ion activity in these systems, suggesting the need for corrections in the models.
Lead (Pb) solubility is commonly limited by dissolution-precipitation reactions of secondary mineral phases in contaminated soils and water. In the research described here, Pb solubility and free Pb2+ ion activities were measured following the precipitation of Pb minerals from aqueous solutions containing sulfate or carbonate in a 1:5 mole ratio in the absence and presence of phosphate over the pH range 4.0-9.0. Using X-ray diffraction and Fourier-transform infrared spectroscopic analysis, we identified anglesite formed in sulfate-containing solutions at low pH. At higher pH, Pb carbonate and carbonate-sulfate minerals, hydrocerussite and leadhillite, were formed in preference to anglesite. Precipitates formed in the Pb-carbonate systems over the pH range of 6 to 9 were composed of cerussite and hydrocerussite, with the latter favored only at the highest pH investigated. The addition of phosphate into the Pb-sulfate and Pb-carbonate systems resulted in the precipitation of Pb-3(PO4)(2) and structurally related pyromorphite minerals and prevented Pb sulfate and carbonate mineral formation. Phosphate increased the efficiency of Pb removal from solution and decreased free Pb2+ ion activity, causing over 99.9% of Pb to be precipitated. Free Pb2+ ion activities measured using the ion-selective electrode revealed lower values than predicted from thermodynamic constants, indicating that the precipitated minerals may have lower K-SP values than generally reported in thermodynamic databases. Conversely, dissolved Pb was frequently greater than predicted based on a speciation model using accepted thermodynamic constants for Pb ion-pair formation in solution. The tendency of the thermodynamic models to underestimate Pb solubility while overestimating free Pb2+ activity in these systems, at least in the higher pH range, indicates that soluble Pb ion-pair formation constants and K-SP values need correction in the models.
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