4.6 Article

Low-Temperature Synthesis and Catalytic Activity of Cobalt Ferrite in Nitrous Oxide (N2O) Decomposition Reaction

Journal

CATALYSTS
Volume 11, Issue 8, Pages -

Publisher

MDPI
DOI: 10.3390/catal11080889

Keywords

cobalt ferrite; mechanochemical synthesis; iron oxalate; cobalt oxalate; nitrous oxide; decomposition; catalyst

Funding

  1. [FZZW 2020-0010]

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The highest catalytic activity of cobalt ferrite nanoparticles in the reaction of nitrous oxide (N2O) decomposition was reported to be 98.1% at 475 degrees Celsius, with the catalysts' structure and catalytic properties correlated and characterized through various tests including X-ray diffraction, thermal analysis, and scanning electron microscopy.
Cobalt ferrite (CoFe2O4) nanoparticles were synthesized and investigated as a catalyst in the reaction of nitrous oxide (N2O) decomposition. Cobalt ferrite was synthesized by solid-phase interaction at 1100 degrees C and by preliminary mechanochemical activation in a roller-ring vibrating mill at 400 degrees C. The nanoparticles were characterized by X-ray diffraction (XRD), synchronous thermal analysis (TG and DSC) and scanning electron microscopy (SEM). A low-temperature nitrogen adsorption/desorption test was used to evaluate the catalytic activity of the cobalt ferrite nanoparticles. Correlations between the structure and catalytic properties of the catalysts are reported. The highest catalytic activity of CoFe2O4 in the reaction of nitrous oxide decomposition was 98.1% at 475 degrees C for cobalt ferrite obtained by mechanochemical activation.

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