4.6 Article

Multivariate Modeling of Mechanical Properties for Hot Runner Molded Bioplastics and a Recycled Polypropylene Blend

Journal

SUSTAINABILITY
Volume 13, Issue 14, Pages -

Publisher

MDPI
DOI: 10.3390/su13148102

Keywords

bioplastics; multivariate analysis; injection molding; thermal degradation

Funding

  1. Mold-Masters Ltd.
  2. Milacron Inc.

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The study compared four sustainable materials processed using a hot runner mold, finding minimal variation in mechanical properties. Reductions in mechanical properties were correlated with thermal degradation, which could be minimized by lowering melt temperature and cycle time, leading to a reduced environmental impact of injection molding processes.
Four sustainable materials including a recycled polypropylene blend, polybutylene adipate terephthalate, and two grades of polylactic acid are compared to a reference isotactic polypropylene. Tensile specimens were produced using a two-cavity, hot runner mold with fully automatic cycles per standard industrial practices to investigate the effect of melt temperature, injection velocity, cycle time, and screw speed on the mechanical properties. Multiple regression and principal component analyses were performed for each of the materials. Results indicated that all the materials were readily processed using a hot runner, and the mechanical properties exhibited minimal variation. To the extent that losses in mechanical properties were observed, the results indicated that the losses were correlated with thermal degradation as independently characterized by thermal gravimetric analysis. Such losses can be minimized by reducing melt temperature and cycle time, leading to a reduction of the environmental impact of injection molding processes.

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