Journal
NANO ENERGY
Volume 87, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.nanoen.2021.106226
Keywords
Microstructure; Crystal structure; Nanotwins; Stacking faults; Perovskite; TEM
Categories
Funding
- ARC
- Australian Centre for Advanced Photovoltaics (ACAP) Postdoctoral Fellowship, Australia
Ask authors/readers for more resources
The addition of CsCl/MACl additives has been found to stabilize the cubic FAPbI3 perovskite, leading to a lattice contraction and changes in the optical bandgap. This results in reduced defects, improved photoluminescence yield, and enhanced device performance, with a maximum efficiency of 21.98% measured for the 10 mol% CsCl perovskite layer.
The incorporation of Cl anion and MA/Cs cations into FAPbI3 perovskite has been shown to dramatically improve solar cell performance. However, the microscopic properties of hybrid metal halide perovskite materials are not well understood yet, and it is still unclear how ion incorporation stabilizes the cubic FAPbI3 perovskite. In this work, we conduct a systematic study on the effect of the CsCl/MACl additives on the microstructure, crystal structure, and defects (nanotwins and stacking faults) of FA-based perovskite solar cells (PSCs). We find that the cubic alpha-phase in pure FAPbI3 is unstable with evidence of additional phases in the experimental electron diffraction analyses, namely the hexagonal 6-phase, the cubic supercell structure (with double the lattice constant of the alpha-phase) and a rhombohedral phase. The addition of CsCl/MACl effectively stabilizes the cubic FAPbI3 with a 2 x 2 x 2 supercell expansion and the Im3 space group. X-ray diffraction and photoluminescence studies show that the addition of CsCl/MACl results in a change in both the lattice parameter and the optical bandgap, respectively. The lattice contraction is a result of the incorporation of Cs/MA cations and Cl anion in the FAPbI3 perovskites. Moreover, the addition of CsCl is shown to minimize the density of defects and improve the photoluminescence yield as well as the minority carrier lifetime of the perovskite films. All of these factors contribute to the improved device performance with a maximum efficiency of 21.98% measured for the 10 mol% CsCl perovskite layer.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available