4.6 Article

Recovery of Critical Metals from Aqueous Sources

Journal

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 9, Issue 35, Pages 11616-11634

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.1c03005

Keywords

Critical metals; Saline water sources; Mining impacts; Extraction technologies

Funding

  1. National Institute of Environmental and Health Sciences (NIEHS) Superfund Program (SRP) [P42 ES004940]

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The study explores the feasibility of extracting critical metals from U.S. saline aqueous sources as an alternative to hardrock ore mining, with a focus on reducing environmental impact and improving domestic manufacturing capabilities. The research identifies potential aqueous sources and processes for recovery of metals, highlighting the potential for decreasing reliance on international supply chains.
Critical metals, identified from supply, demand, imports, and market factors, include rare earth elements (REEs), platinum group metals, precious metals, and other valuable metals such as lithium, cobalt, nickel, and uranium. Extraction of metals from U.S. saline aqueous, emphasizing saline, sources is explored as an alternative to hardrock ore mining. Potential aqueous sources include seawater, desalination brines, oil- and gas-produced waters, geothermal aquifers, and acid mine drainage, among others. A feasibility assessment reveals opportunities for recovery of lithium, strontium, magnesium, and several REEs from select sources, in quantities significant for U.S. manufacturing and for reduction of U.S. reliance on international supply chains. This is a conservative assessment given that water quality data are lacking for a significant number of critical metals in certain sources. The technology landscape for extraction and recovery of critical metals from aqueous sources is explored, identifying relevant processes along with knowledge gaps. Our analysis indicates that aqueous mining would result in much lower environmental impacts on water, air, and land than ore mining. Preliminary assessments of the economics and energy consumption of recovery show potential for recovery of critical metals.

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