4.6 Article

Nutrient Removal in Sequential Batch Polishing Ponds

Journal

WATER
Volume 13, Issue 11, Pages -

Publisher

MDPI
DOI: 10.3390/w13111584

Keywords

polishing pond; pH change; nutrient removal; flow-through and sequential batch regimes; ammonia desorption; phosphate precipitation

Funding

  1. National Research Council (CNPq) [430.392]

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The main issue with waste stabilization ponds is the inability to remove nutrients, which can be efficiently tackled by polishing ponds after anaerobic pretreatment. The pH level in the ponds is crucial for nutrient removal, with biological processes in polishing ponds causing pH elevation triggering nutrient removal mechanisms. Oxygen production through photosynthesis dominates in polishing ponds, leading to an increase in pH and facilitating nutrient removal mechanisms.
One of the main problems of waste stabilization ponds (WSP) is that they cannot remove nutrients when treating wastewater. Polishing ponds (PP) can efficiently remove nitrogen and phosphorus from effluents after efficient anaerobic pretreatment. It shown that the feasibility of nutrient removal is directly related to the pH that is established in the ponds. WSP normally operate at near neutral pH, but the biological processes that develop in PP tend to cause an elevation of pH and this, in turn, triggers the mechanisms of nutrient removal in ponds. In PP oxygen production by photosynthesis predominates over the oxidation of organic material. The net oxygen production has an equivalent CO2 consumption and this induces an increase in pH. The mechanism for nitrogen removal was identified as the desorption of ammonia from the liquid phase of the ponds. It was established that in ponds with a uniform concentration profile in the liquid phase the process developed in accordance with Fick's law. The governing mechanism of phosphorus removal was precipitation with ions present in the wastewater, presumably calcium and magnesium. Polishing ponds can be operated with two different hydrodynamic regimes: flow-through (FTPP) and sequential batch (SBPP) ponds. The SBPP have the advantage that the pH elevation is more rapid, and that the final pH is higher.

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