4.7 Article

Mechanical, Thermal, Electrical Characteristics and EMI Absorption Shielding Effectiveness of Rubber Composites Based on Ferrite and Carbon Fillers

Journal

POLYMERS
Volume 13, Issue 17, Pages -

Publisher

MDPI
DOI: 10.3390/polym13172937

Keywords

absorption shielding; electromagnetic interference; manganese-zinc ferrite; carbon nanotubes; carbon black

Funding

  1. Slovak Research and Development Agency [APVV-16-0136, APVV-19-0091]

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Rubber composites were fabricated with manganese-zinc ferrite and carbon-based fillers, and their electromagnetic parameters, thermal characteristics, and mechanical properties were investigated. The results showed that ferrite provided absorption shielding efficiency to the composites, with varying effects at different frequencies.
In this work, rubber composites were fabricated by incorporation of manganese-zinc ferrite alone and in combination with carbon-based fillers into acrylonitrile-butadiene rubber. Electromagnetic parameters and electromagnetic interference (EMI) absorption shielding effectiveness of composite materials were examined in the frequency range 1 MHz-3 GHz. The influence of ferrite and fillers combination on thermal characteristics and mechanical properties of composites was investigated as well. The results revealed that ferrite imparts absorption shielding efficiency to the composites in tested frequency range. The absorption shielding effectiveness and absorption maxima of ferrite filled composites shifted to lower frequencies with increasing content of magnetic filler. The combination of carbon black and ferrite also resulted in the fabrication of efficient EMI shields. However, the EMI absorption shielding effectiveness was lower, which can be ascribed to higher electrical conductivity and higher permittivity of those materials. The highest conductivity and permittivity of composites filled with combination of carbon nanotubes and ferrite was responsible for the lowest absorption shielding effectiveness within the examined frequency range. The results also demonstrated that combination of ferrite with carbon-based fillers resulted in the enhancement of thermal conductivity and improvement of mechanical properties.

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