Viscoelastic Properties of Epoxidized Natural Rubber/Poly(lactic acid) PLA/ENR Blends Containing Glycidyl-POSS and Trisilanolisooctyl-POSS as Functional Additives

The glycidyl-POSS (Polyhedral Oligomeric Silsesquioxanes, Polysilsesquioxane, POSS) (Gly-POSS) and trisilanolisooctyl-POSS (HO-POSS) were applied as functional additives influencing on the viscoelastic properties of the dynamic vulcanized PLA/ENR (poly(lactic acid)/epoxidized natural rubber) blends. The plasticizing effect of HO-POSS on PLA/ENR melt, leading to the decrease of complex viscosity at 160 degrees C, was observed. After the incorporation of Gly-POSS into PLA/ENR blends the complex viscosity increased confirming that the epoxy groups of Gly-POSS were able to react with the functional groups of ENR and the groups present at the end of PLA chains. The incorporation of Gly-POSS into 40:60 PLA/ENR blend provided significant enhancement of the storage shear modulus G' at 30 degrees C. Furthermore, the glass transition temperatures T-g of ENR phase for PLA/ENR/Gly-POSS blends were shifted to higher values of temperature as compared with blends modified by HO-POSS. Strong reduction of the elongation at break E-b for 40:60 PLA/ENR/Gly-POSS blend indicated that Gly-POSS particles acted as multifunctional cross-links reducing elasticity of the material. The modification of 40:60 PLA/ENR blend by HO-POSS molecules led to lower values of composting coefficient K-C indicating stronger deterioration of the mechanical properties that resulted from more intense degradation processes occurring during disposal in soil.

Automated summary

Glycidyl-POSS and trisilanolisooctyl-POSS were used as functional additives in PLA/ENR blends, with Gly-POSS increasing complex viscosity and storage shear modulus, while HO-POSS acted as a plasticizer in the melt. Gly-POSS also shifted the glass transition temperatures of ENR phase to higher values, indicating stronger cross-linking effects.