4.6 Article

Evaluation of the Protection Ability of a Magnesium Hydroxide Coating against the Bio-Corrosion of Concrete Sewer Pipes, by Using Short and Long Duration Accelerated Acid Spraying Tests

Journal

MATERIALS
Volume 14, Issue 17, Pages -

Publisher

MDPI
DOI: 10.3390/ma14174897

Keywords

concrete bio-corrosion; sulfuric acid corrosion control; magnesium hydroxide coating; sewerage pipe systems; acid spraying test

Funding

  1. European Union
  2. Greek national funds through the Operational Program Competitiveness, Entrepreneurship and Innovation, under the call RESEARCH-CREATE-INNOVATE [T1EDK-02355]

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The study focused on developing a magnesium hydroxide coating to protect concrete pipes from Microbiologically Induced Corrosion, with tests showing satisfactory anti-corrosion properties and adhesion ability, maintaining the concrete surface pH in the alkaline region during acid spraying tests.
The Microbiologically Induced Corrosion (MIC) of concrete sewer pipes is a commonly known problem that can lead to the destruction of the system, creating multiple public health issues and the need for costly repair investments. The present study focuses on the development of a magnesium hydroxide coating, with optimized properties to protect concrete against MIC. The anti-corrosion properties of the respective coating were evaluated by using short and long duration accelerated sulfuric acid spraying tests. The coating presented satisfying adhesion ability, based on pull-off and Scanning Electron Microscopy (SEM) analysis measurements. The surface pH of the coated concrete was maintained at the alkaline region (i.e., > 8.0) throughout the duration of all acid spraying tests. The consumption of the coating, due to the reaction (neutralization) with sulfuric acid, was confirmed by the respective mass and thickness measurements. The protection ability of this coating was also evaluated by recording the formation of gypsum (i.e., the main corrosion product of concrete) during the performed tests, by X-ray Diffraction (XRD) analysis and by the Attenuated Total Reflectance (ATR) measurements. Finally, a long duration acid spraying test was additionally used to evaluate the behavior of the coating, simulating better the conditions existing in a real sewer pipe, and the obtained results showed that this coating is capable of offering prolonged protection to the concrete substrate.

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