4.8 Review

Organic Negative Electrode Materials for Metal-Ion and Molecular-Ion Batteries: Progress and Challenges from a Molecular Engineering Perspective

Journal

ADVANCED ENERGY MATERIALS
Volume 11, Issue 32, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202101562

Keywords

conjugated dicarboxylates; di-azo compounds; ion-batteries; organic negative electrode materials; Schiff bases; viologens

Funding

  1. ANR funding research agency [ANR-13-PRGE-0012]
  2. Conseil Regional de Picardie
  3. FRS-FNRS [J.0111.16 Equinox, J.0043.18-MESOPOL, U.N011.18-DEMIST]
  4. Agence Nationale de la Recherche (ANR) [ANR-13-PRGE-0012] Funding Source: Agence Nationale de la Recherche (ANR)

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Organic batteries are gaining momentum in sustainable energy storage due to their lower environmental impact and structural versatility. While positive electrode chemistries have received extensive attention, there is a lack of critical analysis in the negative electrode field.
In the critical area of sustainable energy storage, organic batteries are gaining momentum as strong candidates thanks to their lower environmental footprint and great structural versatility. A plethora of organic materials have been proposed and evaluated as both positive and negative electrode materials. Whereas positive electrode chemistries have attracted extensive attention in the context of practical research and advances overviews, the negative electrode field remains poorly analyzed from a critical point of view. This review summarizes and provides an assessment of different classes of organic compounds with potential applications as negative electrode materials for metal-ion and molecular-ion batteries. The impact of molecular design on the electrochemical performance and guidelines for remaining challenges are highlighted.

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