4.8 Review

Metal-Catalyzed Metathesis of Fluorinated Alkenes: Still a Current Major Challenge

Journal

ACS CATALYSIS
Volume 11, Issue 19, Pages 12307-12323

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acscatal.1c03414

Keywords

olefin metathesis; fluoroalkenes; ruthenium; molybdenum; fluorine chemistry

Funding

  1. Normandie Universite (NU)
  2. Region Normandie
  3. Centre National de la Recherche Scientifique (CNRS), Universite de Rouen Normandie (URN)
  4. INSA Rouen Normandie, Labex SynOrg [ANR-11-LABX-0029]
  5. graduate school for research XLChem [ANR-18-EURE-0020]
  6. Innovation Chimie Carnot (I2C)
  7. MESRI
  8. Institut Universitaire de France (IUF)
  9. CNRS (Programme de Prematuration CNRS 2020)

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This article presents a review of the challenges in using fluoroalkenes in ring-closing metathesis and cross-metathesis, highlighting the major developments in this field in recent years.
Whereas the olefin metathesis is recognized as a powerful tool to produce alkene, the use of fluoroalkenes in metathesis-catalyzed reactions still remains a major current challenge. Herein, we presented the main developments in that field both in ring-closing metathesis and cross-metathesis, highlighting the major improvements of these past years.

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