Journal
JOURNAL OF NATURAL FIBERS
Volume 19, Issue 14, Pages 7391-7405Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/15440478.2021.1946883
Keywords
Cotton; plasma; dielectric barrier discharge; aging; antimicrobial activity; silver
Categories
Funding
- Ministry of Education, Science and Technological Development of the Republic of Serbia
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Plasma pretreatment of raw cotton fibers combined with silver sorption enhances the antimicrobial activity of fabrics, with significantly higher silver sorption observed when conducted seven days after plasma treatment, highlighting the importance of plasma aging as a factor in fibers' functionalization.
In this work, plasma pretreatment of raw cotton fibers combined with silver sorption was used for the preparation of antimicrobial fabrics. Special attention was given to the aging effect investigated seven days after plasma treatment. Raw cotton fabrics were modified with atmospheric pressure dielectric barrier discharge (DBD) in air, nitrogen, and oxygen. After plasma treatment, surface morphology and chemistry were characterized by atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS), respectively, molecular weight distribution and functional groups profile in cellulose were determined by GPC-MALLS with fluorescence labeling, while sorption properties were evaluated through wettability and moisture sorption measurements. Silver sorption was performed either immediately after treatment or seven days after plasma treatment, in order to investigate the aging effect on the sorption of Ag+. Antimicrobial activity was tested using agar diffusion test against S. aureus, E.coli, and C. albicans. Results have shown that silver sorption is improved and significantly higher when sorption is performed seven days after plasma treatment and consequently antimicrobial activity is also enhanced. This work confirms the significance of plasma aging in natural cellulose fibers' functionalization which presents yet another variable that should be taken into account when planning the procedure for fibers functionalization.
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