Journal
TALANTA
Volume 232, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.talanta.2021.122394
Keywords
Polypyrrole; Solid-phase microextraction; Volatile organic compounds; Gas chromatography
Categories
Funding
- National Science Centre (Poland) [2019/35/N/ST4/04363]
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The study successfully developed a method for synthesis of polypyrrole coating material and its application in solid-phase microextraction. The coating material was evaluated using various physico-chemical methods, showing good stability in extracting VOCs with low limit of detection values.
The aim of the study was to develop an approach for synthesis of polypyrrole coating material and further fabrication of solid-phase microextraction fiber by direct electropolymerization on a stainless-steel wire. Surface morphology, porosity and thermal stability were evaluated by different physico-chemical methods. Synthesized polypyrrole fiber was successfully applied for extraction of VOCs such as benzene, toluene, ethylbenzene, p-xylene, phenol and dodecane. Utilization of polypyrrole fiber for extraction of VOCs was assessed by HS-SPME coupled to gas chromatography with flame ionization detection (GC-FID). Solid-phase microextraction parameters for their simultaneous analysis were optimized using Box-Behnken design and accounted for 49.7 min for extraction time, 30 degrees C for extraction temperature and 17.2 min for equilibration time. In addition, the coating showed good reproducibility (RSD < 12.22%), while the values of limit of detection were in the range of 0.59-283.33 ng/mL.
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