Journal
SYNTHESIS-STUTTGART
Volume 54, Issue 3, Pages 565-569Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1648-2821
Keywords
electrochemistry; C-H activation; directing groups; transition-metal catalysis; biaryls
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Funding
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany's Excellence Strategy [EXC2033-390677874, SFB/TRR88 3MET, FOR 982/1 UNODE]
- Bundesministerium fur Bildung und Forschung (BMBF)
- state of Nordrhein-Westfalen (NRW) (Center of Solvation Science, ZEMOS)
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The article summarizes recent advances in the synthesis of biaryls through electrooxidative processes, with a particular focus on electrooxidative C-H/C-M couplings and dehydrogenative couplings.
The use of electricity as an inexpensive and waste-free oxidant opens up new opportunities for the development of sustainable C-H functionalization reactions. Herein we summarize recent advances in the synthesis of biaryls through electrooxidative processes involving transition-metal-catalyzed ortho -directed C-H activation. A particular focus is set on electrooxidative C-H/C-M couplings and dehydrogenative couplings.
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