Journal
SYNTHESIS-STUTTGART
Volume 53, Issue 18, Pages 3351-3354Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1518-9010
Keywords
palladium; polymer; reduction; silane; sulfur
Categories
Funding
- DIC Corporation
- National Institute of Advanced Industrial Science and Technology (AIST)
- JSPS [19K05481]
- Fujimori foundation
- Grants-in-Aid for Scientific Research [19K05481] Funding Source: KAKEN
Ask authors/readers for more resources
A new method is presented in this study for the reductive cleavage of the solvent-insoluble poly(phenylene sulfide) main chain using triethylsilane as a hydrogen source under palladium/IcHex catalytic conditions. Efficient formation of benzene and bis(triethylsilyl) sulfide as a sulfide source was observed after the reaction. This method is suitable for gram-scale operations.
The solvent-insoluble poly(phenylene sulfide) main chain was reductively cleaved by using triethylsilane as a hydrogen source under palladium/IcHex catalytic conditions. After the reaction, benzene and bis(triethylsilyl) sulfide as a sulfide source were formed efficiently. This method could be operated on a gram scale.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available