4.7 Article

Pulsed laser remelting supersonic plasma sprayed Cr3C2-NiCr coatings for regulating microstructure, hardness and corrosion properties

Journal

SURFACE & COATINGS TECHNOLOGY
Volume 418, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2021.127258

Keywords

Pulsed laser wave remelting; Supersonic plasma spraying; Cr3C2-NiCr coatings; Corrosion resistance

Funding

  1. Guangdong Basic and Applied Basic Research Foundation [2020A1515110849]
  2. Shandong Provincial Natural Science Foundation [ZR2020QE023]
  3. Fundamental Research Funds of Shandong University [2019HW001]

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The evolution in microstructure and corrosion resistance of pulsed laser-remelted Cr3C2-NiCr coatings was investigated, showing significant improvements in hardness and corrosion resistance.
Supersonic atmosphere plasma sprayed Cr3C2-NiCr coatings have been gradually used for protecting industrial components from the severe wear and corrosion attack. In this study, the pulsed laser technique was applied to remelt the deposited Cr3C2-NiCr coatings. The evolution in microstructure and corrosion resistance between the as-sprayed coating and pulsed laser remelted coating was carefully investigated. It is found that desirable metallurgical bonding was achieved between the pulsed laser processed coating and the substrate. After pulsed laser remelting treatment, the metastable phase disappeared and the coating was composed of equilibrium phases of Cr2C3 and Ni-crystal. Interestingly, the morphology of the newly formed carbides became regular and the high-speed Marangoni flow inside the molten pool facilitated their homogeneous distribution. Overall, the porosity decreased from 4.3% of the as-sprayed coating to 1.1% of the laser-treated coating while the carbide volume fraction increased from 49% to 70%. Due to that the coating microstructure became more homogeneous and denser after pulsed laser remelting, the hardness and corrosion resistance were greatly improved.

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