4.7 Article

Form-stable paraffin/graphene aerogel/copper foam composite phase change material for solar energy conversion and storage

Journal

SOLAR ENERGY MATERIALS AND SOLAR CELLS
Volume 226, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.solmat.2021.111083

Keywords

High thermal conductivity; Light-to-thermal energy conversion; Solar energy storage; Paraffin; graphene aerogel; copper foam composite PCM

Funding

  1. National Natural Science Foundation of China [U1507201]
  2. Guangdong-Hong Kong joint innovation projects [2016A050503020]

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Novel form-stable composite phase change materials were prepared for solar energy conversion and storage, with significantly higher thermal conductivities and excellent light-to-thermal energy conversion efficiency.
Sustainable utilization of solar energy with a more compact solar heating system is a significant research. In this study, a novel form-stable composite phase change material (PCM) was prepared for application in solar energy conversion and storage. Paraffin as PCM was encapsulated in the matrix consist of copper foam (CF) loaded with graphene aerogel (GA) in order to improve thermal conductivity, prevent leakage and convert solar energy to thermal energy. The melting temperature and the latent heat of the composite PCMs were determined to estimate thermal storage performance. The thermal conductivities of composite PCMs measured by transient plane heat source method were more than 9 times higher than that of paraffin. Besides, the composite PCMs showed uniform temperature distribution and perfect shape-stabilization when heated. Furthermore, the composite PCMs exhibited an excellent light-to-thermal energy conversion efficiency (up to 97%) in the experiment of light-tothermal energy conversion, which demonstrated the potential of the composite PCM for solar energy conversion and storage.

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