4.7 Article

Ozone detection in the ppt-level with rGO-ZnO based sensor

Journal

SENSORS AND ACTUATORS B-CHEMICAL
Volume 338, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2021.129779

Keywords

rGO; Nanocomposite; ZnO; Laser processing; Gas sensor; Ozone

Funding

  1. Sao Paulo Research Foundation's [2018/07517-2, 2019/22899-1, 2013/07296-2]
  2. CNPq
  3. Capes

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This paper discusses a novel synthesis procedure for rGO-ZnO nanocomposites, involving UV laser radiation for GO reduction and RF-magnetron sputtering for ZnO nanoparticle deposition on the rGO surface. The resulting material can operate at high temperatures and exhibit a detection limit of 100 ppt, outperforming pure ZnO with a detection limit around 1 ppb.
Although several studies have explored the rGO-ZnO nanocomposites gas sensing properties towards many gases, only a few are devoted to ozone detection. This paper explores a novel synthesis procedure of rGO-ZnO nanocomposites based upon a two-step physical process. Namely, a reduction process of GO carried out using UV laser radiation followed by a deposition of ZnO nanoparticles on the rGO surface by RF-magnetron Sputtering. Our results demonstrate that the deposition of ZnO on the surface of the rGO film produces a stable and conductive material with a larger surface area. Consequently, this material is able to operate at high temperatures and exhibited a limit of detection (LOD) in the range of 100 ppt, while pure ZnO exhibited LOD in the vicinity of 1 ppb.

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