Journal
SCIENCE OF THE TOTAL ENVIRONMENT
Volume 777, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.scitotenv.2021.145683
Keywords
Biodiesel; Nanocatalyst; Heterogeneous catalyst; Trans esterification; Bioenergy
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The formulation of biodiesel using alcoholysis or trans esterification techniques with the right catalyst system is crucial. Chemical and biological catalysts are extensively researched, with challenges in separation and thermal stability for chemical catalysts in homogeneous media. Heterogeneous catalysts have emerged as defensive catalysts with predictive efficiency, while facing setbacks in selectivity and limited activity. Biocatalysts lead in mild operating conditions and good selectivity, but operational costs may be a concern. Nanotechnology plays a pivotal role with nano sized catalysts offering excellent reactivity and shorter reaction times in the alternative fuel industry.
Formulation of biodiesel (C-18 ester links) is attracting lots of attention in recent times owing to their sustainability, economic aspects and simple operational technique. Alcoholysis or trans esterification is the effective technique to yield FAME (fatty acid methyl esters) or biodiesel. The catalyst system is an influential factor for this research and broader choices of catalysts are explored. Chemical and biological catalogues of catalysts include acids, bases, oxides, carbonates and porous ex. zeolites and mesoporous materials. The intensive research on chemical catalysts in homogeneous media points at challenges in separation of catalyst from the products and thermal instability. In the need of major advancements towards convenience, heterogeneous catalysts have evolved as defensive catalyst with predictive efficiency. However, in depth studies these types faces setback in selectivity and limited activity issues. Furthermore, biocatalysts leads in context of mild operating conditions and good selectivity. But, the attractive features get masked with operational costs. Nanotechnology has created niche in this alternative fuel industry based on their excellent reactivity with selectivity and lower reaction time owing to their higher surface area and small pore size. Nano sized catalysts plays a pivotal role in heterogeneous & nbsp;phase catalysts as well as in lipase immobilization. This article will enlighten the knowledge of catalysts applied in biodiesel synthesis, their prospects and challenges in the burgeoning renewable fuel market. The review also covers the pertinence of biodiesel produced using these catalysts and their attractive features. (c) 2021 Elsevier B.V. All rights reserved.
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