Journal
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume 66, Issue 9, Pages 1350-1373Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023621090047
Keywords
complexation; closo-decaborate anion; closo-dodecaborate anion
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This paper provides a summary and discussion on the synthesis and structural features of Zn(II) and Cd(II) complexes with boron cluster anions, as well as the influence of reaction conditions on the composition and structures of the final products. A classification of compounds based on the strength of the metal-boron cage interaction is also presented.
Data on the synthesis and structures of Zn(II) and Cd(II) complexes with boron cluster anions [BnHn](2-) (n = 6, 10, 12), their substituted derivatives, as well as analogs-carboranes and metallaboranes-in the presence of competitive organic ligands are generalized and summarized. The synthesis and structural features of the obtained compounds, isomeric composition of the compounds, and influence of the reaction conditions on the composition and structures of the final products are discussed. A classification of compounds is given depending on the strength of the metal-boron cage interaction.
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