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Foaming and rheological properties of aqueous solutions: an interfacial study

Journal

REVIEWS IN CHEMICAL ENGINEERING
Volume 39, Issue 2, Pages 271-295

Publisher

WALTER DE GRUYTER GMBH
DOI: 10.1515/revce-2020-0060

Keywords

air-water interface; foams; particles; rheology; surfactant

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Although aqueous foam is composed of simple fluids, it shows complex rheological behavior. Understanding this behavior is important for industrial applications in various fields. The stability of foam is related to the air-water interface, and the rheological properties of aqueous foam highly depend on its interfacial properties.
Although aqueous foam is composed of simple fluids, air and water, it shows a complex rheological behavior. It exhibits solid-like behavior at low shear and fluid-like behavior at high shear rate. Therefore, understanding such behavior is important for many industrial applications in foods, pharmaceuticals, and cosmetics. Additionally, air-water interface of bubble surface plays an important role in the stabilizing mechanism of foams. Therefore, the rheological properties associated with the aqueous foam highly depend on its interfacial properties. In this review, a systematic study of aqueous foam are presented primarily from rheology point of view. Firstly, foaming agents, surfactants and particles are described; then foam structure was explained, followed by change in structure under applied shear. Finally, foam rheology was linked to interfacial rheology for the interface containing particles whose surface properties were altered by surfactants.

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