4.7 Article

Explosion behaviors of hydrogen-nitrous oxide mixtures at reduced initial pressures

Journal

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
Volume 153, Issue -, Pages 11-18

Publisher

ELSEVIER
DOI: 10.1016/j.psep.2021.07.010

Keywords

Hydrogen explosion; Nitrous oxide; Maximum explosion pressure; Flame instability

Funding

  1. National Natural Science Foundation of China [12002339, 51874267]
  2. Fundamental Research Funds for the Central Universities [WK2090000031, WK2480000008]

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This study investigated the explosion characteristics of H-2/N2O mixtures at different sub-atmospherical pressures, revealing correlations between maximum explosion pressure and maximum pressure rise rate, and identifying factors influencing these parameters.
In this study, we report the explosion characteristics of H-2/N2O mixtures at fuel-lean side and stoichiometric condition in a 113 L cylindrical vessel. Experiments were performed at different sub-atmospherical pressures (P-0 =10 kPa-40 kPa). Explosion pressure traces were obtained by a pressure transducer mounted on the wall. Meanwhile, the flame morphology was recorded using schlieren visualization. The maximum explosion pressure (P-max) and maximum pressure rise rate ((dp/dt)(max)) were derived and discussed. Results show that two competitive effects (i.e., the adiabatic flame temperature and the molecular number) make the maximum P-max occurring at phi =0.5-0.6. Linear correlations were found between P-max and P-0. Except the adiabatic flame temperature and flame propagation speed, the flame instability was found to participate in dominating the maximum pressure rise rate. For increased initial pressure, the equivalence ratio of the maximum (dp/dt)(max) switches to the lean side due to the enhanced flame instability. Depending on different equivalence ratios, both linear and quadratic correlations were found between (dp/dt)(max) and P-0. (C) 2021 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.

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