4.7 Article

Dispersed spherical shell-shaped palygorskite/carbon/polyaniline composites with advanced microwave absorption performances

Journal

POWDER TECHNOLOGY
Volume 387, Issue -, Pages 277-286

Publisher

ELSEVIER
DOI: 10.1016/j.powtec.2021.04.028

Keywords

Palygorskite; Palygorskite; carbon; polyaniline; Nanoparticle dispersion; Spherical shell; Microwave absorption

Funding

  1. Foundation of State Key Laboratory of HighefficiencyUtilization of Coal and Green Chemical Engineering [2021K19]
  2. Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure [SKL202003SIC]
  3. Anhui International Joint Research Center for Nano Carbonbased Materials and Environmental Health [2020R0109]
  4. Shenzhen Technology University (SZTU)
  5. Natural Science Foundation of Top Talent of SZTU [2019010801002]

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In this study, palygorskite was modified to prepare Pal/C/PANI ternary composites, which exhibit promising electromagnetic absorption performances with potential applications in microwave absorption.
Palygorskite was coated with a thin layer of carbon by using a hydrothermal process with glucose, in order to form palygorskite/carbon (Pal/C) composites, which were then used as a template to load polyaniline through in-situ polymerization, thus obtaining dispersed spherical shell-shaped palygorskite/carbon/polyaniline (Pal/C/ PANI) ternary composites. The Pal/C/PANI composites exhibit promising electromagnetic absorption performances, which can be optimized by adjusting the content of Pal/C. In this case, palygorskite acts as a skeleton and dispersion agent, which effectively prevents the agglomeration of carbon and polyaniline. Due to the improved impedance matching and increased dielectric loss, the Pal/C/PANI composites display an optimal reflec-tion loss of -74 dB at 6.24 GHz, with a maximum effective absorption bandwidth of 4.96 GHz. Such composites could be candidates as high performance microwave absorbers. (c) 2021 Elsevier B.V. All rights reserved.

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