4.4 Article

Two-Step Flash-Light Sintering of Copper-Based Inkjet-Printed Patterns onto Polymer Substrates Used in Flexible Electronic Devices

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/pssa.202000775

Keywords

copper nanoparticles; flash-light sources; inkjet printing; two-step sintering

Funding

  1. National Research Foundation (NRF) of Korea (MIST) [2019R1F1A1060586]
  2. ONSEM Semiconductor Project
  3. National Research Foundation of Korea [2019R1F1A1060586] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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High-speed flash-light sintering was used to fabricate highly conductive copper-based inkjet patterns on flexible substrates for lightweight devices. A two-step sintering process resulted in patterns with high density, low resistivity, and long-term stability, showing potential for practical applications.
High-speed flash-light sintering to fabricate inkjet patterns on the flexible substrates employed in lightweight devices is used. A two-step sintering process, i.e., presintering to cause slight necking of copper nanoparticles (CNPs) and final sintering to complete densification, is used to sinter copper-based inkjet patterns. These patterns are more dense and less resistive than those formed via one-step sintering. The specific resistivity of the pattern created using only the second sintering step is 2.65 x 10(-7) omega m and that of the two-step pattern is 0.84 x 10(-7) omega m, and the value shows little change over 180 days. Two-step-sintered patterns on a polyimide substrate exhibit very dense microstructures, surface porosity <7%, and no damage. Thus, highly conductive copper-based inkjet patterns on a flexible substrate are successfully fabricated.

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