4.8 Article

Direct C(sp3)-H Cyanation Enabled by a Highly Active Decatungstate Photocatalyst

Journal

ORGANIC LETTERS
Volume 23, Issue 14, Pages 5501-5505

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c01846

Keywords

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Funding

  1. Samsung Science and Technology Foundation [SSTF-BA1601-12]
  2. National Research Foundation of Korea [NRF-2019R1A2C2086875, NRF-2021R1A5A6002803, NRF-2015H1A2A1033766]
  3. National Research Foundation of Korea [2015H1A2A1033766] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A highly efficient, direct C(sp(3))-H cyanation method was developed under mild photocatalytic conditions, allowing for the direct cyanation of various C(sp(3))-H substrates with excellent functional group tolerance. Complex natural products and bioactive compounds can be efficiently cyanated using this method.
A highly efficient, direct C(sp(3))-H cyanation was developed under mild photocatalytic conditions. The method enabled the direct cyanation of various C(sp(3))-H substrates with excellent functional group tolerance. Notably, complex natural products and bioactive compounds were efficiently cyanated.

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