Journal
ORGANIC LETTERS
Volume 23, Issue 19, Pages 7412-7417Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c02600
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Funding
- Foundation of the Department of Education of Guangdong Province [2018KZDXM070, 2019KZDXM052, 2021KTSCX140]
- Science Foundation for Young Teachers of Wuyi University [2019td06]
- College Students Innovation and Entrepreneurship Training Program [S2020211349091, 2019cx01, 2020cx26]
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This study developed a reversible hydrogen-deuterium exchange reaction for nonactivated olefins, achieving reversible exchange between ordinary olefins and deuterated olefins. By using the lowest cost D2O without precious metal catalysts and ligands, a broad spectrum of functional groups compatibility was achieved.
Herein we have developed a reversible hydrogen-deuterium exchange reaction of nonactivated olefins. By using EtOCS2K as a mediator, the H/D exchange reaction was realized through repeated addition and elimination reactions, demonstrating reversible H/D exchange between ordinary olefins and deuterated olefins. Using the lowest cost D2O without precious metal catalysts and ligands, a broad spectrum of compatibility of functional groups was achieved.
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